What is 4-Ethylphenylboronic acid CAS 63139-21-9? Properties, uses, specifications, and supplier information

18, Aug. 2026

 

What Is 4-Ethylphenylboronic Acid CAS 63139-21-9? Properties, Uses, Specifications, and Supplier Information

4-Ethylphenylboronic acid, identified by CAS No. 63139-21-9, is an aromatic boronic acid used primarily as a building block in organic synthesis. Its molecular formula is commonly represented as C8H11BO2, with a calculated molecular weight of approximately 149.98 g/mol. The molecule contains a phenyl ring, an ethyl substituent in the para position, and a boronic acid group that can participate in palladium-catalyzed cross-coupling reactions. In practical purchasing, buyers should confirm identity, assay, water content, appearance, packaging, and batch-specific analytical documentation before approving the material for production or research.

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Identity and Core Properties

4-Ethylphenylboronic acid belongs to the family of arylboronic acids and is also described as 4-(ethyl)phenylboronic acid or para-ethylphenylboronic acid. The CAS number 63139-21-9 distinguishes this compound from other positional isomers, such as 2-ethylphenylboronic acid and 3-ethylphenylboronic acid. Correct positional identity is important because the location of the ethyl group can influence reaction behavior, steric effects, and the properties of the final product.

At room temperature, this material is generally handled as a solid, although exact color, particle form, and physical appearance may vary by supplier and batch. Its boronic acid group is chemically reactive and can interact with diols, water, and other nucleophilic species under suitable conditions. Storage should therefore follow the supplier’s safety data sheet and product specification, with attention to moisture exposure, container closure, temperature, and compatibility with other stored chemicals.

Parameter Typical identification or purchasing reference
Product name 4-Ethylphenylboronic acid
CAS number 63139-21-9
Molecular formula C8H11BO2
Calculated molecular weight Approximately 149.98 g/mol
Functional group Arylboronic acid

Core Functions and Chemical Uses

Building block for cross-coupling chemistry

The main function of 4-ethylphenylboronic acid is to provide a 4-ethylphenyl group in carbon-carbon bond-forming reactions. Its most recognized role is as an aryl partner in Suzuki-Miyaura coupling, where an arylboronic acid reacts with an aryl or vinyl halide in the presence of a suitable catalyst and base. The resulting biaryl or substituted alkene can be used in medicinal chemistry, agrochemical research, materials development, and specialty synthesis.

The para-ethyl substituent can be useful when a target molecule requires additional hydrophobic character or a specific electronic and steric profile. However, the suitability of this reagent depends on the reaction substrate, catalyst system, solvent, base, temperature, and purification strategy. I recommend treating it as a functional intermediate rather than assuming that every coupling protocol will provide the same conversion or selectivity.

Other research applications

Beyond Suzuki coupling, arylboronic acids may be used in method development, sequential synthesis, and exploratory reactions involving boron-containing intermediates. Researchers may also evaluate this compound when designing libraries of substituted aromatic molecules. These applications are usually project-specific, so the appropriate grade and quantity depend on whether the material is intended for screening, process development, analytical reference work, or scale-up.

Application Scenarios

  • Medicinal chemistry: preparation of substituted biaryl compounds and analogues during lead discovery.
  • Agrochemical research: synthesis of aromatic intermediates for screening and structure-activity studies.
  • Specialty chemicals: production of functional aromatic intermediates for further transformation.
  • Process research: evaluation of reaction conditions before selecting a manufacturing route.
  • Academic and industrial laboratories: small-scale synthesis, reaction optimization, and method comparison.

For commercial development, the most important question is not simply whether the compound is available, but whether its quality profile remains consistent across the required quantity. A material suitable for milligram-scale discovery work may require additional documentation, tighter impurity control, or a different packaging format before it is used in a larger process. Buyers should define the intended application before requesting a quotation.

Types, Grades, and Material Options

4-Ethylphenylboronic acid may be offered in different package sizes and quality levels depending on the supplier’s manufacturing and distribution model. Common distinctions include research grade, synthesis grade, and a customer-specific specification for process development. These labels are not always standardized across suppliers, so I advise comparing the actual certificate of analysis rather than relying only on the grade name.

Material options can also include different particle sizes, packaging formats, and documentation packages. A laboratory buyer may require a small bottle with an analytical certificate, while an industrial customer may need larger packaging, lot reservation, production scheduling, and technical support. If the compound is sensitive to moisture or prolonged storage conditions in a specific process, the buyer should discuss packaging and handling requirements before order confirmation.

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Key Specifications to Confirm

A robust purchasing specification should clearly identify the compound and define measurable acceptance criteria. At minimum, I recommend reviewing the CAS number, molecular formula, molecular weight, assay method, assay result, water content where relevant, residual solvents, and impurity profile. The certificate of analysis should be linked to the actual production or packing lot supplied.

Specification area What buyers should verify
Identity CAS No. 63139-21-9, chemical name, and analytical identification
Assay Supplier-defined acceptance level, commonly quoted as a percentage on the product specification
Appearance Color, physical form, and any stated limits for visible foreign matter
Water and solvents Limits appropriate for the customer’s reaction and storage requirements
Impurities Known process-related impurities and chromatographic reporting approach
Packaging Container material, net weight, closure, labeling, and transport conditions

Purity requirements should be connected to the application rather than selected automatically. For example, a discovery screen may prioritize availability and analytical information, whereas a process route may require tighter control of trace impurities that affect catalyst performance or downstream purification. If a buyer needs a defined assay, I can review the requested target with the available manufacturing specification instead of making an unsupported assumption about suitability.

Buyer Selection Factors

Quality and analytical evidence

The first selection factor is reliable identity and lot-level quality evidence. Buyers should request a certificate of analysis, a safety data sheet, and, when necessary, representative analytical data such as HPLC, NMR, GC, or water analysis. The exact test package should match the risk of the application and the customer’s internal release procedure.

Supply continuity and commercial terms

Availability, minimum order quantity, lead time, packaging, and shelf-life information can materially affect project planning. These details may change according to inventory status, production scheduling, export requirements, and order volume. I recommend asking for a written quotation that separates product price from packaging, documentation, transportation, and any special testing charges.

Regulatory and logistics review

Before import or distribution, the purchasing team should review applicable chemical inventory, labeling, transport, and workplace requirements in the destination market. A supplier can provide documentation support, but the buyer remains responsible for confirming local compliance for the intended use. This review is especially important when the product will be transferred between laboratories, manufacturing sites, or countries.

Maison Chemical Supplier Support

At Maison Chemical, we support B2B customers seeking 4-Ethylphenylboronic acid CAS 63139-21-9 for research, development, and commercial sourcing. We can discuss the required quantity, target specification, packaging format, delivery destination, and documentation before preparing a quotation. Our role is to help customers compare the requested quality profile with the available supply route in a clear and practical way.

For a technical inquiry, please provide the expected order quantity, intended application, required assay or impurity limits, preferred packaging, and target delivery date. If you are evaluating the compound for a new synthesis, sharing the reaction stage or downstream requirement can also help us identify relevant documentation and handling information. Product availability, lead time, and commercial terms should be confirmed for each individual order.

Key Takeaways

  • 4-Ethylphenylboronic acid is an arylboronic acid identified by CAS No. 63139-21-9.
  • Its commonly cited molecular formula is C8H11BO2, with a calculated molecular weight of approximately 149.98 g/mol.
  • Its primary value is as a 4-ethylphenyl building block for cross-coupling and related organic synthesis.
  • Buyers should verify assay, identity, impurities, water content, packaging, documentation, and lot-specific availability.
  • Maison Chemical can review quantity, specification, packaging, and delivery requirements for a B2B quotation.

Conclusion: Is It the Right Intermediate for Your Project?

4-Ethylphenylboronic acid CAS 63139-21-9 is a specialized aromatic building block most directly associated with Suzuki-Miyaura and related synthetic applications. It may be a suitable choice when a project requires incorporation of a para-ethyl-substituted phenyl group, but final suitability depends on the reaction route, quality requirements, and supply conditions. The next practical step is to define your target specification and quantity, then compare supplier documentation and lead time.

Maison Chemical can help you evaluate the sourcing requirements for this compound and prepare a supply proposal based on your application. Contact our sales team with your desired quantity, purity target, packaging preference, destination, and schedule so we can provide product and commercial information for your review.

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